Relation between growth dynamics and the spatial distribution of intrinsic defects in self-assembled colloidal crystal films

Herein we establish a clear relation between the parameters that govern the growth dynamics and the structural quality of colloidal crystal films. We report an optical analysis of the spatial distribution of intrinsic defects in colloidal crystal films and correlate our results with a theoretical model describing the growth dynamics of such lattices. We find that the amount of defects fluctuates periodically and decreases along the growth direction of the lattice. We demonstrate that these spatial variations are a direct consequence of the temporal oscillations of the crystal film formation velocity, which are inherent to the colloidal particle deposition process.Ministerio de Ciencia y Educación MAT2004-0302

Relation between growth dynamics and the spatial distribution of intrinsic defects in self-assembled colloidal crystal films

Herein we establish a clear relation between the parameters that govern the growth dynamics and the structural quality of colloidal crystal films. We report an optical analysis of the spatial distribution of intrinsic defects in colloidal crystal films and correlate our results with a theoretical model describing the growth dynamics of such lattices. We find that the amount of defects fluctuates periodically and decreases along the growth direction of the lattice. We demonstrate that these spatial variations are a direct consequence of the temporal oscillations of the crystal film formation velocity, which are inherent to the colloidal particle deposition process. © 2008 American Institute of Physics.Peer Reviewe

Integration of Photonic Crystals into Flexible Dye Solar Cells: A Route toward Bendable and Adaptable Optoelectronic Devices Displaying Structural Color and Enhanced Efficiency

Herein is presented what is believed to be the fi rst example of integration of photonic structures in a fl exible optoelectronic device. The resulting devices may be designed to display any color in the visible range and, simultaneously, present enhanced power conversion effi ciency as a consequence of the increased light harvesting caused by the colored back refl ection. The achievement results from the incorporation of nanoparticle-based multilayers with photonic crystal properties that are modifi ed to be compatible with the chemical and physical processing of fl exible nanocrystalline titania electrodes of dye solar cells. The photovoltaic performance of these colored fl exible cells remains unaltered after one hundred bending cycles, thus showing the high-mechanical stability of the ensemble. These devices reunite most characteristics required for building integration or for the construction of solar window panes, such as light weight, stability upon bending, adaptability, and color. This work may trigger promising applications of these highly adaptable and versatile photonic crystals in other fl exible devicesEuropean Union 307081, 622533Ministerio de Economía y Competitividad MAT2014-54852-

Effect of extinction on the high-energy optical response of photonic crystals

An analysis of the optical response of photonic crystals in the high-order band energy range is herein presented. High and abruptly fluctuating specular reflectance is predicted for perfect lattices at those energies even in the absence of any photonic gap or pseudogap. As optical extinction is gradually introduced, it is possible to reproduce experimental results found in the literature and which have recently been the subject of an intense debate. Band structure calculations demonstrate that extinction is extraordinarily amplified in the high-energy range and is responsible for the features so far observed in that range in real crystalsConsejo Superior de Investigaciones Científicas 2005AR0070Universidad de Buenos Aires ANPCYT-BID 802Agencia Nacional de Promoción Científica y Tecnológica OC-AR03-14099Ministerio de Educación y Ciencia MAT2005-0302

Panchromatic Porous Specular Back Reflectors for Efficient Transparent Dye Solar Cells

6 páginas, 4 figuras, 1 tablaA panchromatic specular reflector based dye solar cell is herein presented. Photovoltaic performance of this novel design is compared to that of cells in which standard diffuse scattering layers are integrated. The capability of the proposed multilayer structures to both emulate the broad band reflection of diffuse scattering layers of standard thickness (around 5 microns) and give rise to similarly high light harvesting and power conversion efficiencies, yet preserving the transparency of the device, is demonstrated. Such white light reflectors are comprised of stacks of different porous optical multilayers, each one displaying a strong reflection at a complementary spectral range, and are designed to leave transmittance unaltered in a narrow red-frequency range at which the sensitized electrode shows negligible absorption, thus allowing to see through the cell. The reflectance bandwidth achieved is three times as broad as the largest previously achieved with any photonic structure integrated in a dye solar cell.The research leading to these results has received funding from 55 the European Research Council under the European Union's Seventh Framework Programme (FP7/2007-2013)/ERC grant agreement n° 307081 (POLIGHT), the Spanish Ministry of Economy and Competitiveness under grants MAT2011-23593 and CONSOLIDER HOPE CSD2007-00007, and the Junta de 60 Andalucía under grants FQM3579 and FQM5247.The authors also thank the Unit of Information Resources for Research of the Spanish National Research Council (URICI-CSIC) for the co-financing of this publication in Open Access.Peer reviewe

Effect of temperature variations on equilibrium distances in levitating parallel dielectric plates interacting through Casimir forces

We study at thermal equilibrium the e ect of temperature deviations around room temperature on the equi- librium distance (deq) at which thin lms made of Te on, silica or polystyrene immersed in glycerol levitate over a silicon substrate due to the balance of Casimir, gravity, and buoyancy forces. We nd that the equi- librium nature (stable or unstable) of deq is preserved under temperature changes, and provide simple rules to predict whether the new equilibrium position will occur closer or further from the substrate at the new temperature. These rules depend on the static permittivities of all materials comprised in the system ("(m) 0 ) and the equilibrium nature of deq. Our designed dielectric con guration is excellent for experimental obser- vation of thermal e ects on the Casimir force indirectly detected through the tunable equilibrium distances (with slab thickness and material properties) in levitation mode.Peer reviewe

Photon Management in Dye Sensitized Solar Cells

Peer Reviewe

Physical origin of the high energy optical response of three-dimensional photonic crystals

The physical origin of the optical response observed in three-dimensional photonic crystals when the photon wavelength is equal or lower than the lattice parameter still remains unsatisfactorily explained and is the subject of an intense and interesting debate. Herein we demonstrate for the first time that all optical spectra features in this high energy region of photonic crystals arise from electromagnetic resonances within the ordered array, modified by the interplay between these resonances with the opening of diffraction channels, the presence of imperfections and finite size effects. AU these four phenomena are taken into account in our theoretical approach to the problem, which allows us to provide a full description of the observed optical response based on fundamental phenomena as well as to attain fair fittings of experimental results.Consejo Superior de Investigaciones Científicas 2005AR0070Universidad de Buenos Aires ANPCYT-BID 802Agencia Nacional de Promoción Científica y Tecnológica OC-AR03-14099Ministerio de Ciencia y Educación MAT2005-0302

Interplay between crystal-size and disorder effects in the high-energy optical response of photonic crystal slabs

Experimental reflectance spectra have been obtained for colloidal crystals whose widths ranged from one to several sphere monolayers, and their features in the higher order band energy range have been reproduced theoretically. In order to fit the measured data, optical extinction has been introduced in the theoretical model, which accounts for structure imperfections and disorder, the main sources of losses in an actual measurement. A complex spectrum in the high frequency region is observed even for one ordered monolayer, being this peak structure gradually modified as more layers are piled up. This allowed us to identify which peaks are reminiscent of the optical reflectance features of a single close-packed layer and which are the result of building up a three dimensional periodicity. A clear correlation between the amount of extinction introduced in the fitting and the slab width has been found, which demonstrates that wider real crystals produce less diffusely scattered light. At the same time, we find that the optical response of thinner crystals is more robust against the introduction of extinction than that of thicker ones, for which the effect is dramatic.Consejo Superior de Investigaciones Científicas 2005AR0070Universidad de Buenos Aires ANPCYT-BID 802Agencia Nacional de Promoción Científica y Tecnológica OC-AR03-14099Ministerio de Ciencia y Educación MAT2005-0302

Molding with nanoparticle-based one-dimensional photonic crystals: A route to flexible and transferable Bragg mirrors of high dielectric contrast

Self-standing, flexible Bragg mirror films of high refractive index contrast and showing intense and wide Bragg peaks are herein presented. Nanoparticle-based one-dimensional photonic crystals are used as templates to infiltrate a polymer, which provides the multilayer with mechanical stability while preserving the dielectric contrast existing in the mold. Such films can be lifted off the substrate and used to coat another surface of arbitrary shapeMinisterio de Ciencia y Educación MAT2008-02166Junta de Andalucía FQM-357